Hello,
I've completed the steps necessary to enable SMIME within Exchange 2013. I've followed the steps listed here: http://technet.microsoft.com/en-us/library/dn626158(v=exchg.150).aspx
Here is the output from get-smimeconfig in the Exchange Mgmt Shell. When I go to outlook web access and compose an email, I have no option to sign or encrypt. I've requested a user certificate and the cert template I have is set to publish certs to AD. There's no good documentation on how to properly set this up other than the link above which is not very clear.